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Thermodynamic properties of gaseous BaSnO2 and Ba2O2 studied by Knudsen effusion mass spectrometry
Rapid Communications in Mass Spectrometry ( IF 1.8 ) Pub Date : 2020-02-21 , DOI: 10.1002/rcm.8716
Ksenia A. Emelyanova 1 , Sergey M. Shugurov 1 , Andrej I. Panin 1 , Sergey I. Lopatin 1 , Maria A. Panaeva 1
Affiliation  

BaSnO3 is an interesting technical and industrial ceramic, with uses in many areas of electronic technology. Currently, there is great interest in this ceramic material because of its potential as a transparent conductive oxide. Due to its good chemical stability, it is also used as a surface processing material in the synthesis of electroluminophores. When heated, the stannates of alkaline earth metals can pass into the vapor phase with or without dissociation. Until the present investigation, gaseous salts where SnO plays the role of an anion‐forming oxide had been unknown. The formation enthalpy of gaseous Ba2O2 also needed to be determined.

中文翻译:

Knudsen渗流质谱研究气态BaSnO2和Ba2O2的热力学性质

BaSnO 3是一种有趣的技术和工业陶瓷,在电子技术的许多领域都有使用。当前,由于这种陶瓷材料作为透明导电氧化物的潜力而引起了极大的兴趣。由于其良好的化学稳定性,它也可用作电致发光体合成中的表面处理材料。加热时,碱土金属的锡酸盐可以解离或不解离而进入气相。在本研究之前,尚不知道SnO充当形成阴离子的氧化物的气态盐。还需要确定气态Ba 2 O 2的形成焓。
更新日期:2020-02-21
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