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Metal-free synthesis of imino-disaccharides and calix-iminosugars by photoinduced radical thiol-ene coupling (TEC).
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2020/02/21 , DOI: 10.1039/d0ob00198h
Renaud Zelli 1 , Pascal Dumy 1 , Alberto Marra 1
Affiliation  

Radical thiol-ene coupling was exploited for the first time to prepare imino-disaccharides and multivalent iminosugars starting from sugar thiols and iminosugar alkenes or iminosugar thiols and tetra-allylated calixarene, respectively.

中文翻译:

通过光诱导自由基硫醇-烯偶联(TEC)的无金属合成亚氨基二糖和杯糖亚氨基糖。

自由基硫醇-烯偶联是第一次被用来制备亚氨基二糖和多价亚氨基糖,分别从糖硫醇和亚氨基糖烯烃或亚氨基糖硫醇和四烯丙基芳基芳烃开始。
更新日期:2020-04-01
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