100th Anniversary of Macromolecular Science Viewpoint: Fundamentals for the Future of Macromolecular Nitroxide Radicals,ACS Macro Letters

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100th Anniversary of Macromolecular Science Viewpoint: Fundamentals for the Future of Macromolecular Nitroxide Radicals
ACS Macro Letters ( IF 5.1 ) Pub Date : 2020-02-21 , DOI: 10.1021/acsmacrolett.0c00063
Shaoyang Wang ₁ , Alexandra D Easley ₂ , Jodie L Lutkenhaus _{1,

2}

Affiliation

Macromolecular radicals, radical polymers, and polyradicals bear unique functionalities derived from their pendant radical groups. The increasing need for organic functional materials is driving the growth in research interest in macromolecular radicals for batteries, electronics, memory, and imaging. This Viewpoint summarizes the current state-of-knowledge regarding the macromolecular nitroxide radicals’ redox mechanism, conductivity, chain conformation, controlled polymerization, network structure, conjugated forms, and applications. The nitroxide radical group is the focus because it is the most widely studied. Although most literature focuses upon applications, an emerging body of work is highlighting the fundamental physicochemical properties of macromolecular radicals. To this end, this Viewpoint recommends areas of opportunity in fundamental studies and best practices in reporting.

中文翻译：

大分子科学100周年观点：大分子氮氧自由基的未来基础

大分子自由基、自由基聚合物和多自由基具有源自其侧基自由基的独特功能。对有机功能材料日益增长的需求推动了对用于电池、电子产品、存储器和成像的大分子自由基的研究兴趣的增长。该观点总结了当前关于大分子氮氧自由基的氧化还原机理、电导率、链构象、受控聚合、网络结构、共轭形式和应用的知识状态。氮氧自由基基团是焦点，因为它是研究最广泛的。尽管大多数文献都侧重于应用，但新兴的工作主体正在强调大分子自由基的基本物理化学性质。为此，

更新日期：2020-02-21

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