The cellulosic component of lignocellulosic biomass can be converted to commercially valuable platform chemicals through pyrolysis provided it is effectively controlled and optimized. This review first discusses the underpinning kinetics and mechanism of cellulose pyrolysis to identify target platform chemicals. Platform chemicals like 5‐hydroxymethyl furfural, 5‐chloromethyl furfural, and levoglucosenone, which are potentially amenable to the pyrolytic conversion of cellulose, are then elucidated. There are laboratory and large‐scale reactor technologies available for converting biomass to bio‐oil but they have not been comprehensively investigated for producing platform chemicals through pyrolysis. This review critically evaluates different reactor types available for developing the catalytic pyrolysis process for converting cellulosic component of biomass to platform chemicals. The fluidized bed reactor stands out as the most suitable reactor technology for the catalytic pyrolysis of cellulose to platform chemicals owing to attributes like short residence time, high heating rate, uniform mixing, efficient heat transfer, and scalability of operations. This article provides perspective on the implementation of this technology for the pyrolysis of the cellulosic component of biomass to platform chemicals. © 2019 Society of Chemical Industry and John Wiley & Sons, Ltd

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用于平台化学品的纤维素快速热解：潜在目标评估和合适的反应器技术

木质纤维素生物质的纤维素组分可以通过热解转化为具有商业价值的平台化学品，只要对其进行有效控制和优化即可。这篇综述首先讨论了纤维素热解确定目标平台化学物质的基础动力学和机理。然后阐明了平台化学物质（如5-羟甲基糠醛，5-氯甲基糠醛和左旋葡糖酮），它们可能适合于纤维素的热解转化。有实验室和大型反应器技术可用于将生物质转化为生物油，但尚未对其进行热解生产平台化学品进行全面研究。该评论严格评估了可用于开发催化热解过程的不同反应器类型，该催化热解过程用于将生物质的纤维素组分转化为平台化学品。流化床反应器因其停留时间短，加热速率高，混合均匀，传热效率高和操作可扩展性等特性而成为最适合将纤维素催化热解为平台化学品的反应器技术。本文提供了有关将生物质的纤维素组分热解为平台化学品的技术实施的观点。©2019年化学工业协会和John Wiley＆Sons，Ltd 流化床反应器因其停留时间短，加热速率高，混合均匀，传热效率高和操作可扩展性等特性而成为最适合将纤维素催化热解为平台化学品的反应器技术。本文提供了有关将生物质的纤维素组分热解为平台化学品的技术实施的观点。©2019年化学工业协会和John Wiley＆Sons，Ltd 流化床反应器因其停留时间短，加热速率高，混合均匀，传热效率高和操作可扩展性等特性而成为最适合将纤维素催化热解为平台化学品的反应器技术。本文提供了有关将生物质的纤维素组分热解为平台化学品的技术实施的观点。©2019年化学工业协会和John Wiley＆Sons，Ltd