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The fluorescent liquid crystal and spiro-silicon bridged compounds based on silafluorene core
Journal of Organometallic Chemistry ( IF 2.1 ) Pub Date : 2020-02-13 , DOI: 10.1016/j.jorganchem.2020.121178
Ping Tang , Liangchun Li , Kai Xiang , Yanmin Li , Shuhong Li , Caihong Xu

Based on silafluorene core, the liquid crystal silafluorene and spiro-silicon bridged silafluorene compounds were synthesized. Apart from higher thermal stability, the obtained compounds containing liquid crystal units demonstrated liquid crystal behavior and fluorescent properties with higher solid fluorescent quantum yield. The spiro-silicon bridged compound displayed good solubility, which led to easy processing. Besides, it exhibited easy preparation and higher emissive fluorescent properties.



中文翻译:

基于硅芴核的荧光液晶和螺硅桥联化合物

在硅芴核的基础上,合成了液晶硅芴和螺硅桥联的硅芴化合物。除了具有更高的热稳定性之外,所获得的包含液晶单元的化合物还具有较高的固体荧光量子产率,表现出液晶行为和荧光性质。螺硅桥连化合物显示出良好的溶解性,从而易于加工。此外,它显示出易于制备和较高的发射荧光性质。

更新日期:2020-02-20
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