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Half-sandwich ruthenium(II) complexes containing biphenylamine based Schiff base ligands: Synthesis, structure and catalytic activity in amidation of various aldehydes
Journal of Organometallic Chemistry ( IF 2.1 ) Pub Date : 2020-02-14 , DOI: 10.1016/j.jorganchem.2020.121175 Veerasamy Nagalakshmi , Raja Nandhini , Veerappan Brindha , Bellie Sundaram Krishnamoorthy , Kasthuri Balasubramani
中文翻译:
含联苯胺基希夫碱配体的半三明治钌(II)配合物:各种醛的酰胺化反应的合成,结构和催化活性
更新日期:2020-02-20
Journal of Organometallic Chemistry ( IF 2.1 ) Pub Date : 2020-02-14 , DOI: 10.1016/j.jorganchem.2020.121175 Veerasamy Nagalakshmi , Raja Nandhini , Veerappan Brindha , Bellie Sundaram Krishnamoorthy , Kasthuri Balasubramani
New half-sandwich ruthenium (II) complexes [η6‒p-cymene)Ru (L1-3)Cl] (1–3) containing biphenylamine based Schiff base ligands (HL1-3) have been synthesized and characterized by analytical and spectroscopic methods. Additionally, the solid state structure of 2 has been determined by single crystal X-ray diffraction study. The complex 2 serves as a catalyst for the amidation of various aldehydes to amides in good yield.
中文翻译:
含联苯胺基希夫碱配体的半三明治钌(II)配合物:各种醛的酰胺化反应的合成,结构和催化活性
新半夹心钌(II)配合物[η 6 - p -cymene)的Ru(L 1-3)CL](1-3型)含有联苯胺希夫碱配体(HL 1-3)已被合成和表征通过分析和光谱方法。另外,已经通过单晶X射线衍射研究确定了2的固态结构。络合物2用作高产率地将各种醛酰胺化为酰胺的催化剂。