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Advances in transition-metal (Zn, Mn, Cu)-based MOFs and their derivatives for anode of lithium-ion batteries
Coordination Chemistry Reviews ( IF 20.3 ) Pub Date : 2020-02-07 , DOI: 10.1016/j.ccr.2020.213221
Ting Li , Yilu Bai , Yong Wang , Hui Xu , Hong Jin

High-performance lithium-ion batteries (LIBs) have attracted intensive attention owing to their use in portable electronic devices, electric automobiles, etc. The theoretical capacity of graphite is 372 mA h g−1, and therefore, graphite cannot satisfy the ever-increasing demand for high-capacity LIBs. Metal-organic frameworks (MOFs) and their derivatives are considered promising anode materials for LIBs owing to their tunable structure, high surface area, and highly porous structure. In this review, recent developments in transition-metal (Zn, Mn, Cu)-based MOFs and their derivatives are discussed for LIBs. Major challenges faced in using MOFs and their derivatives as anode materials are summarized, and strategies are proposed for further enhancing their performance in LIBs. This review is expected to contribute to the development of novel MOFs that could help realize high-performance LIBs.



中文翻译:

锂离子电池阳极过渡金属(Zn,Mn,Cu)基MOF及其衍生物的研究进展

高性能锂离子电池(LIB)由于在便携式电子设备,电动汽车等中的使用而引起了广泛关注。石墨的理论容量为372 mA h g -1因此,石墨不能满足对大容量LIB的不断增长的需求。金属有机骨架(MOF)及其衍生物由于其可调结构,高表面积和高度多孔性而被认为是有前途的LIB阳极材料。在这篇综述中,讨论了基于过渡金属(Zn,Mn,Cu)的MOF及其衍生物的最新进展。总结了使用MOF及其衍生物作为阳极材料所面临的主要挑战,并提出了进一步提高其在LIB中的性能的策略。预期此审查将有助于开发新型MOF,以帮助实现高性能LIB。

更新日期:2020-02-20
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