Application of Crabtree/Pfaltz-Type Iridium Complexes for the Catalyzed Asymmetric Hydrogenation of an Agrochemical Building Block,Organic Process Research & Development

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Application of Crabtree/Pfaltz-Type Iridium Complexes for the Catalyzed Asymmetric Hydrogenation of an Agrochemical Building Block
Organic Process Research & Development ( IF 3.1 ) Pub Date : 2020-03-03 , DOI: 10.1021/acs.oprd.9b00466
Jacob Schneekönig ₁ , Weiping Liu _{1,

2} , Thomas Leischner ₁ , Kathrin Junge ₁ , Christoph Schotes ₃ , Christian Beier ₃ , Matthias Beller ₁

Affiliation

Herein we report improved chemo- and enantioselective hydrogenations of 1-(2,2,4-trimethylquinolin-1(2H)-yl)ethan-1-one (1) toward (R)-1-(2,2,4-trimethyl-3,4-dihydroquinolin-1(2H)-yl)ethan-1-one (2) using well-defined novel Crabtree-type iridium complexes.

中文翻译：

Crabtree / Pfaltz型铱配合物在农药基石催化不对称加氢中的应用

在这里，我们报告1-（2,2,4-三甲基喹啉-1（2 H）-基）乙烷-1-酮（1）向（R）-1-（2,2,4）的化学和对映选择性氢化得到改善-trimethyl-3,4-dihydroquinolin-1（2 H）-yl）ethan-1-one（2）使用定义明确的新型Crabtree型铱配合物。

更新日期：2020-03-03

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