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Efficient formation of γ-valerolactone in the vapor-phase hydrogenation of levulinic acid over Cu-Co/alumina catalyst
Catalysis Communications ( IF 3.4 ) Pub Date : 2020-02-20 , DOI: 10.1016/j.catcom.2020.105967
Daichi Yanase , Rei Yoshida , Shuhei Kanazawa , Yasuhiro Yamada , Satoshi Sato

Vapor-phase hydrogenation of levulinic acid (LA) to γ-valerolactone (GVL) was investigated over Al2O3-supported bimetallic CuCo catalysts with different Cu/Co weight ratios under ambient H2 pressure. The bimetallic Cu-Co/Al2O3 catalyst with a Cu/Co weight ratio of 8/12 exhibits an excellent catalytic activity and stability: it showed a high GVL productivity of 5.46 kg kgcat.−1 h−1 with a GVL selectivity higher than 99% at 250 °C for 24 h. In the characterization of the catalysts, powder X-ray diffraction suggests that bimetallic CuCo particles on the Cu-Co/Al2O3 catalysts are composed of an alloy.



中文翻译:

Cu-Co /氧化铝催化剂上乙酰丙酸气相加氢中γ-戊内酯的高效形成

在Al 2 O 3负载的Cu / Co重量比不同的Al 2 O 3负载双金属Cu Co催化剂上,在环境H 2压力下,研究了乙酰丙酸(LA)的气相加氢成γ-戊内酯(GVL)。Cu / Co重量比为8/12的双金属Cu-Co / Al 2 O 3催化剂具有出色的催化活性和稳定性:显示出5.46 kg kg催化剂的高GVL生产率-1  h -1,在250°C下保持24小时的GVL选择性高于99%。在催化剂的表征中,粉末X射线衍射表明在Cu-Co / Al 2 O 3上的双金属Cu Co颗粒 催化剂由合金组成。

更新日期:2020-02-20
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