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Stereoselective synthesis and properties of glycoazobenzene macrocycles through intramolecular glycosylation.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-02-26 , DOI: 10.1039/c9cc09853d
Chaoqi Lin 1 , Jinbiao Jiao 1 , Stéphane Maisonneuve 1 , Julien Mallétroit 1 , Juan Xie 1
Affiliation  

An intramolecular glycosylation strategy was used to synthesize a series of new glycoazobenzene macrocycles with high α-selectivity and interesting chiroptical properties. The photoisomerization of an azobenzene template influences mainly the efficiency of the glycosylation.

中文翻译:

通过分子内糖基化的立体选择性合成和偶氮糖大环化合物的性质。

分子内糖基化策略被用来合成一系列具有高α-选择性和有趣的手性的新的糖基偶氮大环。偶氮苯模板的光异构化主要影响糖基化的效率。
更新日期:2020-03-19
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