Isosmaragdyrin with an N3C2 core: stabilization of Rh(i) and organo-Pt(ii) complexes.,Chemical Communications

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Isosmaragdyrin with an N3C2 core: stabilization of Rh(i) and organo-Pt(ii) complexes.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-02-27 , DOI: 10.1039/d0cc00214c
Mainak Das ₁ , Sangya Chitranshi , M Murugavel , B Adinarayana , Cherumuttathu H Suresh , A Srinivasan

Affiliation

Isosmaragdyrin with an N3C2 core is successfully achieved by introducing a 2,6-di-m-phenylpyridine unit. The core is utilized to stabilize the Rh(i) ion in the N-Rh(i)-N bonding mode and the Pt(ii) ion in the (N^C)N fashion to form an unsymmetrical pincer-type organometallic complex.

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