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Isosmaragdyrin with an N3C2 core: stabilization of Rh(i) and organo-Pt(ii) complexes.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-02-27 , DOI: 10.1039/d0cc00214c
Mainak Das 1 , Sangya Chitranshi , M Murugavel , B Adinarayana , Cherumuttathu H Suresh , A Srinivasan
Affiliation  

Isosmaragdyrin with an N3C2 core is successfully achieved by introducing a 2,6-di-m-phenylpyridine unit. The core is utilized to stabilize the Rh(i) ion in the N-Rh(i)-N bonding mode and the Pt(ii) ion in the (N^C)N fashion to form an unsymmetrical pincer-type organometallic complex.

中文翻译:

具有N3C2核心的异麦角铁蛋白:稳定Rh(i)和有机Pt(ii)配合物。

通过引入2,6-二-间-苯基吡啶单元成功地实现了具有N3C2核心的异麦格糊精。该核用于稳定N-Rh(i)-N键合模式的Rh(i)离子和(N ^ C)N形式的Pt(ii)离子,从而形成不对称的钳型有机金属络合物。
更新日期:2020-03-26
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