Two-dimensional (2D) metal-organic frameworks (MOFs) belong to a subgroup of MOFs reminiscent of graphite and covalent organic frameworks (COFs). In the past decade, conductive 2D MOFs have received increasing attention due to their relatively high charge carrier mobility and low resistivity that originate from in-plane charge delocalization and extended π conjugation within the layers. This review comprises the current state-of-the-art of the representative progress in theoretical exploration and electronic applications of conductive 2D MOFs. Special emphasis is placed on the intrinsic relations between the structural factors and the electronic properties of conductive 2D MOFs. This review will provide guidance for researchers to design and synthesize conductive 2D MOFs for advanced applications.

中文翻译：

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导电二维金属有机骨架的理论探索和电子应用。

二维（2D）金属有机框架（MOF）属于MOF的一个子类，让人联想到石墨和共价有机框架（COF）。在过去的十年中，导电2D MOF由于其相对较高的载流子迁移率和较低的电阻率而受到越来越多的关注，这是由于面内电荷离域和层内π共轭扩展引起的。这篇综述涵盖了导电2D MOF的理论探索和电子应用领域中的代表性技术的最新进展。特别强调的是导电2D MOF的结构因素与电子特性之间的内在联系。这篇综述将为研究人员为高级应用设计和合成导电2D MOF提供指导。