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Highly Effective 2‐D layer Structured Titanium Carbide Electrode for Dye‐sensitized and Perovskite Solar Cells
ChemElectroChem ( IF 3.5 ) Pub Date : 2020-02-18 , DOI: 10.1002/celc.201902159
Jing‐yuan Ma 1 , Mengyao Sun 1 , Yan‐an Zhu 1 , Huawei Zhou 2 , Kezhong Wu 1 , Jun Xiao 3 , Mingxing Wu 1
Affiliation  

In this study, 2‐D layer structured Ti3C2 is synthesized using etching method under lower temperature, and then it is applied in dye‐sensitized and perovskite solar cells as counter electrode with higher activity compared with conventional TiC particles counter electrode. The dye‐sensitized solar cells fabricated using 2‐D layer structured Ti3C2 counter electrode achieves a power conversion efficiency of 9.57%, much higher than that of the counterpart device fabricated using TiC particles counter electrode (7.37%). The excellent activity of Ti3C2 electrode can be attributed to the superior charge transfer and mass transport properties owing to the specific 2‐D layer structure. Moreover, the fabricated 2‐D layer structured Ti3C2 is attempted to be applied in perovskite solar cells, thereby achieving a power conversion efficiency of 7.78% without further optimization. Thus, it exhibits a potential candidate to the noble metal electrodes.

中文翻译:

适用于染料敏化和钙钛矿太阳能电池的高效二维二维结构化碳化钛电极

在这项研究中,二维层结构的Ti3C2是在较低的温度下通过蚀刻方法合成的,然后与传统的TiC颗粒对电极相比,以更高的活性应用于染料敏化和钙钛矿太阳能电池中。使用二维层结构的Ti3C2对电极制造的染料敏化太阳能电池可实现9.57%的功率转换效率,远高于使用TiC颗粒对电极制造的对等设备(7.37%)。由于特定的二维层结构,Ti3C2电极的出色活性可以归因于优越的电荷转移和传质特性。此外,尝试将制造的二维层结构的Ti3C2应用于钙钛矿太阳能电池,从而实现7的功率转换效率。78%无需进一步优化。因此,它对贵金属电极表现出潜在的候选。
更新日期:2020-02-18
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