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Main Group Metal Complexes in Selective Bond Formations via Radical Pathways.
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2020-02-12 , DOI: 10.1002/chem.202000194
Crispin Lichtenberg 1
Affiliation  

Recent years have witnessed remarkable advances in radical reactions involving main‐group metal complexes. This includes the isolation and detailed characterization of main‐group metal radical compounds, but also the generation of highly reactive persistent or transient radical species. A rich arsenal of methods has been established that allows control over and exploitation of their unusual reactivity patterns. Thus, main‐group metal compounds have entered the field of selective bond formations in controlled radical reactions. Transformations that used to be the domain of late transition‐metal compounds have been realized, and unusual selectivities, high activities, as well as remarkable functional‐group tolerances have been reported. Recent findings demonstrate the potential of main‐group metal compounds to become standard tools of synthetic chemistry, catalysis, and materials science, when operating through radical pathways.

中文翻译:


通过自由基途径选择性形成键的主族金属配合物。



近年来,涉及主族金属配合物的自由基反应取得了显着进展。这包括主族金属自由基化合物的分离和详细表征,还包括高反应性持久或瞬态自由基物种的生成。已经建立了丰富的方法库,可以控制和利用其不寻常的反应模式。因此,主族金属化合物已进入受控自由基反应中选择性成键的领域。曾经属于后过渡金属化合物领域的转化已经实现,并且已经报道了不寻常的选择性、高活性以及显着的官能团耐受性。最近的研究结果表明,当通过自由基途径进行操作时,主族金属化合物有可能成为合成化学、催化和材料科学的标准工具。
更新日期:2020-02-12
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