A facile and direct C–H amination reaction at the 3-positions of BODIPY core was proceeded with high regioselectivity upon treatment with various amines. Spectroscopic properties of the 3-aminoBODIPY were substantially modulated by electron-donating nitrogen atoms. Theoretical calculations had been used to analyze the structure-property relationships and could be well explained for the regioselectivity of amination.

中文翻译：

---

BODIPY核的直接C–H胺化：合成和光谱性质

在用各种胺处理后，在BODIPY核的3位上进行了简便而直接的CH氨基化反应，具有很高的区域选择性。3-氨基BODIPY的光谱性质基本上受供电子氮原子的调节。理论计算已用于分析结构-性质关系，并可以很好地解释胺的区域选择性。