High temperature Fe(III) spin crossover behaviours in three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes,Inorganic Chemistry Frontiers

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High temperature Fe(III) spin crossover behaviours in three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2020-02-04 , DOI: 10.1039/c9qi01560d
Zhi-Jian Ouyang _{1,

2,

3,

4,

5} , Xiao-Ying Mo _{1,

2,

3,

4,

5} , Meng Yang _{1,

2,

3,

4,

5} , Li Zhong _{1,

2,

3,

4,

5} , Wen-Bin Chen _{1,

2,

3,

4,

5} , Song Gao _{2,

5,

6,

7} , Wen Dong _{1,

2,

3,

4,

5}

Affiliation

An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H₃ATD) was used to synthesize three unprecedented Fe^III–M^II–Fe^III (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal Fe^III ions.

中文翻译：

在三种前所未有的FeIII–MII–FeIII（M = Fe，Cd）线性三核络合物中的高温Fe（III）自旋交叉行为

偶氮四唑基-2,7-二羟基萘（H ₃ ATD）的基于偶氮的配体用于合成三种具有不同高温自旋交联（SCO）的前所未有的Fe ^III –M ^II –Fe ^III（M = Fe，Cd）线性三核配合物Fe ^III离子的行为。

更新日期：2020-02-04

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