Stimuli-responsive behaviors of organic charge transfer cocrystals: recent advances and perspectives,Materials Chemistry Frontiers

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Stimuli-responsive behaviors of organic charge transfer cocrystals: recent advances and perspectives
Materials Chemistry Frontiers ( IF 6.0 ) Pub Date : 2020/01/22 , DOI: 10.1039/c9qm00760a
Lingjie Sun _{1,

2,

3,

4,

5} , Fangxu Yang _{1,

2,

3,

4,

5} , Xiaotao Zhang _{1,

2,

3,

4,

5} , Wenping Hu _{1,

2,

3,

4,

5}

Affiliation

Organic cocrystals, as an intelligent design strategy of functional materials, have received extensive attention in the scientific community over recent years. The presence of diverse molecular arrangements and rich intermolecular interactions, in particular intrinsic charge transfer in organic cocrystals, depicts such materials as ideal systems to control and tailor their physical properties for stimuli-responsive applications. However, as a continuous emerging research field, a systematic review to summarize this promising application area remains unexplored. Herein, we focus on recent research progress and potential advantages of organic cocrystals in the field of stimuli response. First, an overview of the basic characteristics of organic charge transfer cocrystals is discussed. Subsequently, the stimuli-responsive behaviors of organic cocrystals under mechanical force, solvent, acid–base, light and heat stimuli are highlighted. Lastly, the future developments and prospects of these materials in a stimuli-responsive field are outlined.

中文翻译：

有机电荷转移共晶体的刺激响应行为：最新进展和观点

近年来，作为功能材料的智能设计策略，有机共晶体受到了科学界的广泛关注。多种分子排列和丰富的分子间相互作用的存在，特别是有机共晶体中固有的电荷转移，将这类材料描述为控制和定制其物理性质以用于刺激响应性应用的理想系统。但是，作为一个不断出现的研究领域，尚未进行系统的综述以总结这一有前途的应用领域。在本文中，我们集中于有机共晶体在刺激反应领域的最新研究进展和潜在优势。首先，讨论有机电荷转移共晶体的基本特性。后来，突出了有机共晶体在机械力，溶剂，酸碱，光和热刺激下的刺激响应行为。最后，概述了这些材料在刺激响应领域的未来发展和前景。

更新日期：2020-03-05

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