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Photoluminescence emission from nanostructured porous preparations of CdS-ZnTiO3 assembled nanoparticles.
Luminescence ( IF 2.9 ) Pub Date : 2020-02-06 , DOI: 10.1002/bio.3784
E Campos-González 1 , G Gonzalez de la Cruz 1 , P Rodriguez-Fragoso 1 , Y E Bravo-García 2 , R Castanedo-Pérez 3 , G Torres-Delgado 3 , O Zelaya-Angel 1
Affiliation  

This study reports the structural and optical properties of CdS/ZnTiO3 nanocomposites prepared using a chemical bath and different titanate concentrations. Commercial ZnTiO3 nanoparticles were introduced into a chemical bath that had been used to produce CdS semiconductor nanoparticles (NPs). Here, the growing CdS crystallites precipitated onto the suspended zinc titanate NPs. X‐ray diffraction patterns revealed that samples of CdS/ZnTiO3 nanopowders were made of cubic ZnTiO3 and hexagonal CdS wurtzite. The morphology of the particles was studied using transmission electron microscopy and scanning electron microscopy images. These images demonstrated the different characteristics of the CdS/ZnTiO3 nanocomposites and their dependence on titanate concentration when placed into the CdS‐growing solution. Photoluminescence spectra showed three main emission bands for the electron transitions in the CdS/ZnTiO3 composite. This composite produced three photoluminescence bands, the intensities of which depended on composite shape, which in turn depended on the relative concentrations of CdS and ZnTiO3.

中文翻译:

CdS-ZnTiO3组装的纳米颗粒的纳米结构多孔制剂的光致发光发射。

这项研究报告了使用化学浴和不同钛酸盐浓度制备的CdS / ZnTiO 3纳米复合材料的结构和光学性质。将商业ZnTiO 3纳米颗粒引入已用于生产CdS半导体纳米颗粒(NP)的化学浴中。在这里,正在生长的CdS微晶沉淀在悬浮的钛酸锌NP上。X射线衍射图谱显示CdS / ZnTiO 3纳米粉的样品由立方晶ZnTiO 3和六角形CdS纤锌矿制成。使用透射电子显微镜和扫描电子显微镜图像研究了颗粒的形态。这些图像证明了CdS / ZnTiO 3的不同特性纳米复合材料及其在CdS生长溶液中对钛酸盐浓度的依赖性。光致发光光谱显示了CdS / ZnTiO 3复合材料中电子跃迁的三个主要发射带。该复合材料产生三个光致发光带,其强度取决于复合材料的形状,而复合材料的形状又取决于CdS和ZnTiO 3的相对浓度。
更新日期:2020-02-06
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