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Practical Synthesis of High‐Performance Amino Tf‐Amide Organocatalysts for Asymmetric Aldol Reactions
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-02-06 , DOI: 10.1002/ajoc.202000048 Hanbin Lu 1 , Jiamin Lv 1 , Canhua Zhou 1 , Terumasa Kato 1 , Yan Liu 1 , Keiji Maruoka 1, 2
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-02-06 , DOI: 10.1002/ajoc.202000048 Hanbin Lu 1 , Jiamin Lv 1 , Canhua Zhou 1 , Terumasa Kato 1 , Yan Liu 1 , Keiji Maruoka 1, 2
Affiliation
The cover art depicts the direct asymmetric aldol reactions of cycloalkanones and substituted benzaldehydes catalyzed by a secondary‐amino aromatic Tf‐amide organocatalyst, affording the corresponding aldol adducts in good yield with good to excellent anti‐diastereo‐ and enantioselectivity. The catalyst efficiently “lightens” the diastereo‐ and enantioselective transformation. The art shows a sky lantern, known as Kongming Light, which is used as a wishing lamp in the traditional Chinese Festivals, such as the Lantern Festival and Mid Autumn Festival. More information can be found in the Communication by Yan Liu, Keiji Maruoka et al.
更新日期:2020-02-07