The interaction of graphite with a gaseous mixture of BrF₃ and Br₂ at room temperature produced fluorinated graphite intercalation compounds with bromine. By changing the concentration of BrF₃ in Br₂ from 6.2 to 2.9 % we were able to obtain matrices of fluorinated graphene layers (C₂F_x)_n with x = 0.76, 0.66, 0.35, 0.25. It was shown that bromine was completely replaced by acetonitrile in the (C₂F_x)_n with x > 0.6, while two types of guests (CH₃CN and Br₂) were present between the layers with the lower fluorine loading. The Van der Waals forces hold CH₃CN molecules in the (C₂F_x)_n host. The interaction of Br₂ molecules with sp²-carbon regions remained in the C₂F_x layers has donor-acceptor type. The models of guest molecules packing in host matrices (C₂F_x)_n are considered using the data on the stoichiometry and X-ray diffraction analysis.

石墨与室温下BrF ₃和Br ₂的气体混合物的相互作用产生了带溴的氟化石墨插层化合物。通过将Br _2中的BrF ₃的浓度从6.2％更改为2.9％，我们可以获得具有x  = 0.76、0.66、0.35、0.25的氟化石墨烯层（C ₂ F _x）_n的矩阵。结果表明，在（C ₂ F _x）_n中，x > 0.6的溴被乙腈完全取代，而两种客体（CH ₃ CN和Br ₂）存在于具有较低氟负载的层之间。范德华力将CH ₃ CN分子保持在（C ₂ F _x）_n主体中。Br ₂分子与保留在C ₂ F _x层中的sp ^2-碳区域的相互作用具有施主-受主类型。利用化学计量和X射线衍射分析的数据，考虑了客体分子堆积在主体基质（C ₂ F _x）_n中的模型。