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Recent progresses in graphene-based (photo)catalysts for reduction of nitro compounds
Molecular Catalysis ( IF 3.9 ) Pub Date : 2020-02-05 , DOI: 10.1016/j.mcat.2019.110758
Mahmoud Nasrollahzadeh , Zahra Nezafat , Mostafa Ghafori Gorab , Mohaddeseh Sajjadi

The rapid progresses in the reduction of nitro compounds represent a potent and extensively utilized transformation, which allows the introduction of amino compounds. From the standpoint of organic chemistry, amines have many applications in the synthesis of drugs, biologically active molecules, pharmaceutical products, dyes, polymers, etc. For this aim and owing to the environmental concerns about toxic nitro contaminants such as 4-nitrophenol (4-NP), up to know, much research has been carried out on the reduction/degradation of nitroarenes for the fabrication of amines using different heterogeneous (nano)catalysts. This review provides the current developments in the area of production, classification and applications of graphene-based catalysts in the reduction of nitro compounds to amines. The application of graphene derivatives in the synthesis of various catalysts is advantageous compared to other catalysts and thus increases the rate of reduction of nitro compounds. The use of these catalysts offers several benefits such as straightforward work-up, high catalytic prowess and recovery.



中文翻译:

石墨烯基(光)催化剂还原硝基化合物的最新进展

硝基化合物还原的快速进展代表了有效且广泛使用的转化,这允许引入氨基化合物。从有机化学的角度来看,胺在药物,生物活性分子,药物产品,染料,聚合物的合成中具有许多应用。。为此目的,由于对有毒硝基污染物(例如4-硝基苯酚(4-NP))的环境关注,迄今为止,人们已经进行了许多有关还原/降解硝基芳烃来制备胺的研究,这些胺是使用不同的异质化合物(纳米催化剂。这篇综述提供了在将硝基化合物还原为胺的过程中石墨烯基催化剂的生产,分类和应用领域的最新进展。与其他催化剂相比,石墨烯衍生物在各种催化剂的合成中的应用是有利的,因此增加了硝基化合物的还原速率。这些催化剂的使用提供了一些好处,例如直接的后处理,高催化能力和回收率。

更新日期:2020-02-06
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