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Effect of Composition of Mg-Al-Oxide Systems on their Catalytic Properties in the Production of 2-Ethyl-1-Hexanol in Vapor-Phase Condensation of 1-Butanol in a Flow System
Theoretical and Experimental Chemistry ( IF 0.7 ) Pub Date : 2019-11-01 , DOI: 10.1007/s11237-019-09626-1
K. V. Valihura , O. V. Larina , P. I. Kyriienko , N. V. Vlasenko , S. O. Soloviev

It is shown that Mg-Al-oxide catalysts in the vapor-phase condensation of 1-butanol to 2-ethyl-1-hexanol in a flow-type reactor are superior in performance to individual Mg and Al oxides on account of achieving optimal surface concentrations and ratios of acid and base sites due to the formation of Mg-O-Al sites at the phase boundary.

中文翻译:

Mg-Al-Oxide 体系的组成对流动系统中 1-丁醇气相冷凝生产 2-Ethyl-1-己醇的催化性能的影响

结果表明,在流动式反应器中 1-丁醇与 2-乙基-1-己醇的气相缩合反应中,Mg-Al-氧化物催化剂的性能优于单独的 Mg-Al-氧化物催化剂,因为可实现最佳表面由于在相界处形成 Mg-O-Al 位点,酸和碱位点的浓度和比率。
更新日期:2019-11-01
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