Abstract

In this review, we discuss the nature and bonding, role of metal acetylacetonates as precursors for nanoparticle research, polymer science, catalysis and their mechanistic aspects, which we believe to provide an illustrative overview of current research directions in this rapidly developing field. The chosen examples within this review reflect the remarkable broadness of nanoparticle research, polymer and applications of metal acetylacetonates as catalysts in organic syntheses. The purpose of this review is to provide recent advancements of several catalytic reactions employing well defined metal enolate complexes. Metal enolates are used in a plethora of catalysed reactions. Several catalytic reactions have been highlighted in this review to show where metal enolate complexes have played a significant role in recent years. The ultimate goal of this effort is towards the development of catalysts that impart the selectivities, reactivity, and atom economy needed for cost-effective approaches to a variety of critical chemical transformations.

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摘要

在这篇综述中，我们讨论了金属乙酰丙酮化物作为纳米颗粒研究，聚合物科学，催化及其机理方面的前体的性质和键合，作用，我们认为这将为该快速发展领域中的当前研究方向提供例证性的概述。本综述中所选择的实例反映了纳米颗粒研究，聚合物的广泛应用以及金属乙酰丙酮化物作为有机合成催化剂的应用。这篇综述的目的是提供使用定义明确的金属烯醇盐配合物的几种催化反应的最新进展。金属烯醇化物用于大量的催化反应中。这篇综述着重介绍了几种催化反应，以显示近年来金属烯醇配合物在哪些方面发挥了重要作用。

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