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Mechanistic investigation of oxidation of glycine and alanine by bis(dihydrogen-tellurto)argentite(III) ion in alkaline medium. A kinetic study
Journal of the Iranian Chemical Society ( IF 2.4 ) Pub Date : 2009 , DOI: 10.1007/bf03245831
S. Huo , C. Song , J. Shan , S. Shen , H. Sun

The oxidation of glycine and alanine by bis(dihydrogen-tellurto)argentite(III) ion was studied by stopped-flow spectrophotometery. The reaction is of first order in Ag(III) complex and has less than unit order in glycine and alanine. A plausible mechanism was proposed form the kinetic studies. The rate equations derived from mechanism found to explain all experimental phenomena. The activation parameters with respect to the rate determining step of the mechanism were calculated.

中文翻译:

碱性介质中双(二氢-弹丸基)银云母(III)离子氧化甘氨酸和丙氨酸的机理研究。动力学研究

通过停止流式分光光度法研究了双(二氢-碲基)银云母(III)离子对甘氨酸和丙氨酸的氧化作用。该反应在Ag(III)络合物中是一级反应,在甘氨酸和丙氨酸中的反应少于单元顺序。从动力学研究中提出了一个合理的机制。从机理得出的速率方程可以解释所有实验现象。计算与该机制的速率确定步骤有关的激活参数。
更新日期:2020-09-12
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