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Structure and Thermal Properties of TmFe2O4 at Various Temperatures and Oxygen Pressures
Doklady Physical Chemistry ( IF 0.9 ) Pub Date : 2019-01-01 , DOI: 10.1134/s0012501619010044
L. B. Vedmid’ , O. M. Fedorova , V. M. Dimitrov , V. F. Balakirev

The stability range of TmFe2O4 was studied at a temperature of 1090°C and reduced oxygen pressure in the gas phase. Using experimental data obtained for TmFe2O4 dissociation in the temperature range of 750–900°C, its thermodynamic characteristics were calculated. The structural transformations in the temperature range from –140 to 140°C associated with charge ordering in this compound were identified.

中文翻译:

TmFe2O4 在不同温度和氧气压力下的结构和热性能

TmFe2O4 的稳定性范围在 1090°C 的温度和气相中降低的氧气压力下进行了研究。使用 TmFe2O4 在 750-900°C 温度范围内解离的实验数据,计算了其热力学特性。在 –140 到 140°C 的温度范围内,确定了与该化合物中的电荷排序相关的结构转变。
更新日期:2019-01-01
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