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Modern Approaches to the Tuning of the Lanthanide(3+) Coordination Compound Luminescent Characteristics: A Review
Theoretical and Experimental Chemistry ( IF 1 ) Pub Date : 2019-11-01 , DOI: 10.1007/s11237-019-09622-5
E. A. Mikhalyova , V. V. Pavlishchuk

The modern concepts underlying the control of luminescence characteristics (quantum yield, intensity, emission color) of lanthanide coordination compounds are analyzed. The influence of the electronic structure of ligands and ions of 4f elements on the luminescent properties of these metal complexes is examined in detail. Approaches for changing the quantum yield values, emission intensity and color are proposed both by the directed design of the coordination sphere of lanthanide ions and the composition of compounds, and by using external stimuli (temperature, wavelength of exciting light).

中文翻译:

调节镧系(3+)配位化合物发光特性的现代方法:综述

分析了控制镧系配位化合物发光特性(量子产率、强度、发光颜色)的现代概念。详细研究了配体和 4f 元素离子的电子结构对这些金属配合物发光性能的影响。改变量子产率值、发射强度和颜色的方法是通过镧系元素离子配位球和化合物组成的定向设计以及使用外部刺激(温度、激发光的波长)提出的。
更新日期:2019-11-01
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