Co-based metal organic frameworks (Co-MOFs) are porous crystalline materials formed by the coupling of metallic cobalt ions and organic ligands. Co₃O₄ based catalysts derived from Co-MOFs have attracted great attention in the field of catalysis. In this paper, some familiar Co-MOFs materials and the latest progress are introduced, such as ZIF-67, Co-MOF-71 and Co-MOF-74. The preparation techniques of these Co-MOFs are described in detail, including co-precipitation, sol–gel method, dipping method, hydrothermal method, solid phase grinding method, self-assembled template method and so on. The research progress of its application in the field of catalytic oxidation reaction is also highlighted. Based on the report of published literatures, we analyzed the design ideas of Co-MOFs materials and put forward the prospect for the future development.

钴基金属有机骨架（Co-MOF）是通过金属钴离子与有机配体的偶联形成的多孔晶体材料。钴₃ O ₄衍生自Co-MOF的铁基催化剂在催化领域引起了极大的关注。本文介绍了一些熟悉的Co-MOFs材料和最新进展，例如ZIF-67，Co-MOF-71和Co-MOF-74。详细描述了这些Co-MOFs的制备技术，包括共沉淀法，溶胶-凝胶法，浸渍法，水热法，固相研磨法，自组装模板法等。重点介绍了其在催化氧化反应领域中的研究进展。基于已发表的文献报道，我们分析了协同MOF材料的设计思路，并提出了未来的发展前景。