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Degradation of Reactive Dye in Aqueous Solution by Fenton, Photo-Fenton Process and Combination Process with Activated Charcoal and TiO 2
Proceedings of the National Academy of Sciences, India Section A: Physical Sciences ( IF 0.8 ) Pub Date : 2019-06-20 , DOI: 10.1007/s40010-019-00618-3
Saurabh K. Patel , Sunil G. Patel , Geeta V. Patel

In the present work, a comparative efficiency of photo-Fenton (PF) treatment process and its combined process with activated carbon (AC) and titanium dioxide (TiO2) have been investigated using reactive yellow 145 as a model compound. These processes are based on in situ production of hydroxyl radical, a highly strong oxidant, which allows the degradation of organic dye until their mineralization into CO2 and H2O. The effect of different process parameters, such as initial dye concentration, pH of the solution, Fe2+ concentration, catalyst and adsorbent loadings, and effect of various systems and irradiation times have been studied. The degradation of the dye was monitored by decolorization and COD analysis and then analyzed by high-performance liquid chromatography and IR analysis. Obtained results showed that PF combined with titanium dioxide (PF-TiO2) for removal of TOC was more efficient than PF or combination with AC. About 73.7% of TOC removal was obtained after 240 min of UV–F–TiO2 process, whereas the PF and UV–F–AC process yielded TOC reduction of 61.5% and 54.8% after 240 min. Mineralization studied reveals that effectiveness of treatment processes for RY145 is UV–F–TiO2 > PF > UV–F–AC > F–AC > F–TiO2.



中文翻译:

Fenton,光-Fenton工艺及活性炭与TiO 2混合工艺对水溶液中活性染料的降解

在目前的工作中,研究了使用活性黄145作为模型化合物的光芬顿(PF)处理工艺及其与活性炭(AC)和二氧化钛(TiO 2)组合工艺的比较效率。这些过程在原位产生羟基自由基,一高度强氧化剂,其允许有机染料的降解,直到它们的矿化成CO的基于2和H 2 O.不同的工艺参数,如初始染料浓度,pH值的影响溶液,Fe 2+已经研究了浓度,催化剂和吸附剂的负载量以及各种系统和照射时间的影响。通过脱色和COD分析监测染料的降解,然后通过高效液相色谱和IR分析进行分析。所得结果表明,PF与二氧化钛(PF-TiO 2)结合去除TOC比PF或与AC结合更有效。在UV-F-TiO 2处理240分钟后,TOC去除量约为73.7%,而PF和UV-F-AC处理在240分钟后,TOC降低了61.5%和54.8%。研究的矿化表明,RY145的处理过程的有效性为UV–F–TiO 2  > PF> UV–F–AC> F–AC> F–TiO 2

更新日期:2019-06-20
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