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Synthesis and characterization of activated carbon produced from waste human hair mass using chemical activation
Carbon Letters ( IF 5.5 ) Pub Date : 2019-10-29 , DOI: 10.1007/s42823-019-00099-9
Derya Bal Altuntaş , Vagif Nevruzoğlu , Meryem Dokumacı , Şafak Cam

In this study, hair waste was converted into active carbon for the first time and its characteristics were analyzed. As chemical activation tool, zinc chloride (ZnCl2) was impregnated and then carbonized under different temperatures (250–300 °C). Scanning Electron Microscope (SEM) images showed an increase in the pore density, radius and volume of pores. X-ray diffraction analysis (XRD) showed that the samples had an amorphous structure. In Fourier-transform infrared (FT-IR) spectroscope analysis, C=C and N–H vibrations observed in 1515–1520 cm−1 wave number of protein molecules were found to disappear with the increase in temperature. With Raman spectroscopy, the behaviors of D peak at 1344 cm−1 wave number and G peak at 1566 cm−1 wave number expressing structure layout in carbonized structures were analyzed depending on the temperatures. Between these intensities, (ID/IG) the rate was found to differ in direct proportion to temperature. XRD spectrums showed that the samples are converted into a more irregular crystal structure. All these results implied that the waste hair mass could be used as an adsorbant material.

中文翻译:

使用化学活化法从废人头发中产生的活性炭的合成与表征

在这项研究中,头发废料首次被转化为活性炭,并对其特性进行了分析。作为化学活化工具,氯化锌(ZnCl 2)浸渍后在不同温度(250–300°C)下碳化。扫描电子显微镜(SEM)图像显示孔密度,孔半径和体积增加。X射线衍射分析(XRD)表明样品具有非晶态结构。在傅立叶变换红外(FT-IR)光谱分析中,发现1515–1520 cm -1处蛋白质分子的波数随温度升高而消失,C = C和N–H振动消失。用拉曼光谱法,在1344 cm -1波数处的D峰和在1566 cm -1处的G峰的行为根据温度对碳化结构中的波数表示结构布局进行了分析。在这些强度之间(I D / I G),发现速率与温度成正比。XRD光谱表明样品被转化为更不规则的晶体结构。所有这些结果暗示废毛团可以用作吸附剂材料。
更新日期:2019-10-29
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