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Kinetic Parameters of Thermal Decomposition of Furazano-1,2,3,4-Tetrazine-1,3-Dioxide and a Binary Solution Based on It
Combustion, Explosion, and Shock Waves ( IF 1.2 ) Pub Date : 2019-09-01 , DOI: 10.1134/s0010508219050150
N. V. Murav’ev , K. A. Monogarov , V. E. Zarko , P. I. Kalmykov , A. N. Pivkina

The kinetic parameters of thermal decomposition of furazano-1,2,3,4-tetrazine-1,3-dioxide (FTDO) and the (75/25) FTDO/dinitrazapentane (DNP) system were experimentally investigated by differential scanning calorimetry. Kissinger kinetic analysis was performed using differential scanning calorimetry data obtained at heating rates of 0.1–5.0 K/min. The thermal decomposition of FTDO and the FTDO/DNP system is found to be a first-order reaction with an activation energy of 185 (FTDO) and 171 kJ/mol (FTDO/DNP).

中文翻译:

Furazano-1,2,3,4-Tetraazine-1,3-Dioxide及其二元溶液热分解动力学参数

Furazano-1,2,3,4-tetrazine-1,3-dioxide (FTDO) 和 (75/25) FTDO/dinitrazapentane (DNP) 系统的热分解动力学参数通过差示扫描量热法进行了实验研究。Kissinger 动力学分析是使用在 0.1–5.0 K/min 的加热速率下获得的差示扫描量热数据进行的。FTDO 和 FTDO/DNP 体系的热分解被发现是一级反应,活化能为 185 (FTDO) 和 171 kJ/mol (FTDO/DNP)。
更新日期:2019-09-01
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