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Production of Methyl Acetate from Methanol in Vapor-Phase Tandem Reactions on Supported Copper–Nickel Catalysts
Theoretical and Experimental Chemistry ( IF 0.7 ) Pub Date : 2019-09-01 , DOI: 10.1007/s11237-019-09617-2
A. Yu. Kapran , V. I. Chedryk , L. M. Alekseenko , P. S. Yaremov , S. M. Orlyk

A method is proposed for the production of methyl acetate by combining vapor-phase reactions of methanol decomposition on a CuO-NiO-ZnO/Al2O3/cordierite catalyst and subsequent carbonylation on nickel–copper catalysts supported on BAU-A activated charcoal (AC) or cordierite. A yield of 21% methyl acetate was obtained on the catalyst containing 11% NiCl2 and 32% CuCl2 on AC.

中文翻译:

在负载型铜镍催化剂上的气相串联反应中由甲醇生产乙酸甲酯

提出了一种通过将甲醇分解在 CuO-NiO-ZnO/Al2O3/堇青石催化剂上的气相反应和随后在 BAU-A 活性炭 (AC) 上负载的镍铜催化剂上羰基化相结合来生产乙酸甲酯的方法。堇青石。在含有 11% NiCl2 和 32% CuCl2 的 AC 催化剂上获得 21% 乙酸甲酯的产率。
更新日期:2019-09-01
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