Frontiers of Materials Science ( IF 2.5 ) Pub Date : 2019-05-22 , DOI: 10.1007/s11706-019-0462-3 Chao Wang , Wu Wang , Ke He , Shantang Liu
Nanocubes derived from pure In2O3 and xPr-In2O3 (x = 1, 2, 3 and 5 mol.%) were synthesized using a facile hydrothermal method, followed by calcination. The morphological and structural characterization demonstrated that as-synthesized samples presented regular cubes that decreased in size with the increase of the Pr doping. The data showed that the sensing performances of sensors based on In2O3 were notably improved after the Pr doping. Among them, the sensor based on 2 mol.% Pr-In2O3 had the best sensing performance towards the triethylamine (TEA) gas, including a high response (Ra/Rg = 260 to 100 ppm TEA gas, which is about 12 times higher than that of the sensor based on pure In2O3), a short response time (2 s), and a low detection limit (0.2 ppm) at 350 °C. The mechanism responsible for the enhancement of sensing performance was attributed to the improvement of the vacancy content of 2 mol.% Pr-In2O3, which promoted the oxidation–reduction reaction with the TEA gas that occurred on the materials surface.
中文翻译:
掺In
使用简便的水热法合成了由纯In 2 O 3和x Pr-In 2 O 3(x = 1、2、3和5 mol。%)衍生的纳米立方,然后进行煅烧。形态和结构表征表明,合成样品呈现规则的立方体,其尺寸随着Pr掺杂的增加而减小。数据表明,Pr掺杂后,基于In 2 O 3的传感器的感测性能得到明显改善。其中,基于2 mol。%Pr-In 2 O 3的传感器对三乙胺(TEA)气体具有最佳的传感性能,包括高响应性(R a / R g = 260至100 ppm TEA气体,约为基于纯In 2 O 3的传感器的12倍),响应时间短(2 s)和低检测限(0.2 ppm) )在350°C。增强传感性能的机理归因于2摩尔%Pr-In 2 O 3的空位含量的提高,这促进了与材料表面发生的TEA气体的氧化还原反应。