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Synthesis, structure and photoluminescence of [Cu(acac)(dppe)] n with novel 1D zigzag chain-like motif
Journal of the Iranian Chemical Society ( IF 2.2 ) Pub Date : 2009 , DOI: 10.1007/bf03246505 Y.-M. Xie , J.-H. Wu
Journal of the Iranian Chemical Society ( IF 2.2 ) Pub Date : 2009 , DOI: 10.1007/bf03246505 Y.-M. Xie , J.-H. Wu
A novel complex [Cu(acac)(dppe)]n (1) [acac = acetylacetone; dppe = 1,2-bis(diphenylphosphino)ethane] was obtained by solution reactions and structurally characterized by X-ray diffraction. The crystal structure analysis indicates that the title complex is characteristic of a polymeric chain formed by the dppe ligands bridging neighboring copper centers. The copper atom is in a distorted tetrahedral geometry. Photoluminescent investigation reveals that the title complex displays a strong emission in bluelight region.
中文翻译:
具有新型一维锯齿形链状基序的[Cu(acac)(dppe)] n的合成,结构和光致发光
一种新型的络合物[Cu(acac)(dppe)] n(1)[acac =乙酰丙酮; 通过溶液反应获得dppe = 1,2-双(二苯基膦基)乙烷,并通过X射线衍射对其结构进行表征。晶体结构分析表明标题配合物是由桥接相邻铜中心的dppe配体形成的聚合物链的特征。铜原子呈扭曲的四面体几何形状。光致发光研究表明标题复合物在蓝光区域显示出强发射。
更新日期:2020-09-12
中文翻译:
具有新型一维锯齿形链状基序的[Cu(acac)(dppe)] n的合成,结构和光致发光
一种新型的络合物[Cu(acac)(dppe)] n(1)[acac =乙酰丙酮; 通过溶液反应获得dppe = 1,2-双(二苯基膦基)乙烷,并通过X射线衍射对其结构进行表征。晶体结构分析表明标题配合物是由桥接相邻铜中心的dppe配体形成的聚合物链的特征。铜原子呈扭曲的四面体几何形状。光致发光研究表明标题复合物在蓝光区域显示出强发射。