In the present work, using sonochemical method, novel mercury (II) metal–organic supramolecule with nano-rods shape, [Hg(1,10-phen)Cl₂]_n (1) (1,10-then = 1,10-phenanthroline) was prepared. The impact of the synthesis elements including duration, irradiation power, and concentrations was investigated and enhanced. Nano rods and nano flowers morphologies were obtained by applying diverse sonication time, power and concentration. The samples were categorized via IR spectroscopy, scanning electron microscopy, single crystal X-ray analysis, elemental analysis, X-ray photoelectron spectroscopy and X-ray powder diffraction. Based on the X-ray structure analysis, it was observed that two nitrogen atoms of the “1,10-phen” ligand and four chloride bridging atoms with symmetrical octahedral geometry and a HgN₂Cl₄ donor set coordinate the Hg(II) atom. A one-dimensional zig-zag polymer is created by the crystal forms. The nearby chains attached to π–π of nearby aromatic circles of “1,10-phen” and other weak interactions. Hence, as a result of the weak interactions, it is possible for the 1D zig-zag arrangement to create a three dimensional metal–organic coordination polymer. Through thermolyzing the compound 1 with oleic acid as a surfactant at the temperature of 180 °C, HgO nanoparticles were obtained. Using SEM, the as-synthesized HgO nanoparticles were further tested in terms of the morphology and size.

中文翻译：

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研究超声波辐射功率，反应物浓度和反应时间对新型纳米汞（II）金属-有机配位聚合物形态的影响

在本工作中，采用声化学方法，制备了新型的具有纳米棒状[Hg（1,10-phen）Cl ₂ ] _n（1的汞（II）金属-有机超分子。）（1,10-then = 1,10-菲咯啉）的制备。研究并增强了合成元素的影响，包括持续时间，辐照功率和浓度。通过应用不同的超声处理时间，功率和浓度获得纳米棒和纳米花形态。通过IR光谱，扫描电子显微镜，单晶X射线分析，元素分析，X射线光电子光谱和X射线粉末衍射对样品进行分类。根据X射线结构分析，观察到“ 1,10-phen”配体的两个氮原子和对称的八面体几何形状的四个氯化物桥接原子和HgN ₂ Cl ₄供体集合协调Hg（II）原子。一维之字形聚合物是由晶体形式产生的。附近的链连接到附近的“ 1,10-phen”芳香环的π-π和其他弱相互作用。因此，由于弱相互作用，一维之字形排列有可能产生三维金属-有机配位聚合物。通过用油酸作为表面活性剂在180℃下加热化合物1，获得HgO纳米颗粒。使用SEM，对合成后的HgO纳米颗粒的形态和尺寸进行了进一步测试。