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Fabrication of manganese ferrite/graphene oxide nanocomposites for removal of nickel ions, methylene blue from water
Chemical Physics ( IF 2.3 ) Pub Date : 2020-02-03 , DOI: 10.1016/j.chemphys.2020.110700
Lu Thi Mong Thy , Nguyen Hoan Kiem , Tran Hoang Tu , Lu Minh Phu , Doan Thi Yen Oanh , Hoang Minh Nam , Mai Thanh Phong , Nguyen Huu Hieu

Nowadays, environmental pollution has increasingly serious effects to human health, especially water pollution. Heavy metals and organic dyes are major environmental pollutants. In this study, manganese ferrite/graphene oxide (MnFe2O4/GO) nanocomposites were fabricated by in situ method and used as an adsorbent for the removal of nickel ions (Ni2+), methylene blue (MB) from water. The MnFe2O4/GO nanocomposite with a mass ratio of MnFe2O4 to GO of 1:1 (FGO2) had high adsorption capacity and was easily separated by external magnetic field. The adsorption data of FGO2 fitted well with a pseudo-second-order kinetic and Langmuir isotherm models. The maximum adsorption capacities of FGO2 for Ni2+ and MB were determined to be 152.67 and 89.29 mg/g, respectively. MnFe2O4/GO nanocomposite was characterized by Fourier transform infrared spectroscopy, X-ray diffraction, transmission electron microscopy, Brunauer-Emmett-Teller (BET) specific surface area, and vibrating sample magnetometer (VSM). FGO2 had the BET specific surface area of 78.46 m2/g and VSM of 28.74 emu/g. Based on these results, the FGO2 could be considered as a highly efficient adsorbent for removing Ni2+, MB from water.



中文翻译:

锰铁氧体/氧化石墨烯纳米复合材料的制备以去除水中的镍离子和亚甲基蓝

如今,环境污染对人类健康的影响日益严重,尤其是水污染。重金属和有机染料是主要的环境污染物。本研究采用原位法制备锰铁氧体/氧化石墨烯(MnFe 2 O 4 / GO)纳米复合材料,并作为吸附剂从水中去除镍离子(Ni 2+),亚甲基蓝(MB)。所述锰铁2 ö 4 / GO纳米复合材料与锰铁的质量比2 Ò 4至GO的1:1(FGO2)具有高的吸附容量和容易被外部磁场分离。FGO2的吸附数据与拟合良好伪二阶动力学和Langmuir等温模型。FGO2对Ni 2+和MB的最大吸附容量分别确定为152.67和89.29 mg / g。MnFe 2 O 4 / GO纳米复合材料的特征在于傅立叶变换红外光谱,X射线衍射,透射电子显微镜,Brunauer-Emmett-Teller(BET)比表面积和振动样品磁力计(VSM)FGO 2的BET比表面积为78.46m 2 / g,VSM为28.74emu / g。基于这些结果,FGO 2被认为是从水中去除Ni 2 +,MB的高效吸附剂。

更新日期:2020-02-03
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