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Hydroboration–Oxidation of Terpenoids in Targeted Syntheses of Low-Molecular-Mass Bioregulators
Chemistry of Natural Compounds ( IF 0.8 ) Pub Date : 2020-01-01 , DOI: 10.1007/s10600-020-02935-1
M. P. Yakovleva , V. A. Vydrina , A. A. Kravchenko , G. Yu. Ishmuratov

Examples of hydroboration–oxidation of natural mono-, sesqui-, di-, and triterpenoids are reviewed. Diborane, BH 3 ·THF, BH 3 ·Me 2 S, disiamylborane, thexylborane, dicyclohexylborane, 9-borabicyclo[3,3,1]nonane (9-BBN), and diisopinocampheylborane are used as the hydroboration reagents; H 2 O 2 mixed with KOH, NaOH, and NaOAc, as the oxidants. Most of the examples address mono- and sesquiterpenoids with far fewer describing di- and triterpenoids.

中文翻译:

低分子生物调节剂靶向合成中萜类化合物的硼氢化-氧化

综述了天然单萜、倍半萜、二萜和三萜的硼氢化-氧化的例子。乙硼烷、BH 3 ·THF、BH 3 ·Me 2 S、二异戊基硼烷、二甲苯基硼烷、二环己基硼烷、9-硼双环[3,3,1]壬烷(9-BBN)和二异松蒎基硼烷用作硼氢化试剂;H 2 O 2 与作为氧化剂的 KOH、NaOH 和 NaOAc 混合。大多数例子涉及单萜和倍半萜,而描述二萜和三萜的例子要少得多。
更新日期:2020-01-01
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