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A sustainable access to ynones through laccase/TEMPO-catalyzed metal- and halogen-free aerobic oxidation of propargylic alcohols in aqueous medium
Catalysis Communications ( IF 3.7 ) Pub Date : 2020-01-28 , DOI: 10.1016/j.catcom.2020.105946
Alana B.V. Silva , Emmanuel D. Silva , Alcindo A. dos Santos , Jefferson L. Princival

Tuning laccase/TEMPO-catalyzed aerobic oxidation of secondary propargylic alcohols in aqueous media was accomplished in order to efficiently synthesize ynones. This study led to the formulation of an effective and sustainable catalytic method for the preparation of mono- and bis-substituted ynones compared with traditional oxidative methods.



中文翻译:

在水性介质中通过漆酶/ TEMPO催化的炔丙醇的无金属和无卤素好氧氧化来可持续获得炔酮

完成了漆酶/ TEMPO催化在水性介质中的仲炔丙醇的需氧氧化,以有效合成炔酮。这项研究导致与传统的氧化方法相比,制定了一种有效且可持续的催化方法来制备单取代和双取代的炔酮。

更新日期:2020-01-30
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