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Advances in Conjugated Microporous Polymers.
Chemical Reviews ( IF 51.4 ) Pub Date : 2020-01-28 , DOI: 10.1021/acs.chemrev.9b00399
Jet-Sing M Lee 1 , Andrew I Cooper 1
Affiliation  

Conjugated microporous polymers (CMPs) are a unique class of materials that combine extended π-conjugation with a permanently microporous skeleton. Since their discovery in 2007, CMPs have become established as an important subclass of porous materials. A wide range of synthetic building blocks and network-forming reactions offers an enormous variety of CMPs with different properties and structures. This has allowed CMPs to be developed for gas adsorption and separations, chemical adsorption and encapsulation, heterogeneous catalysis, photoredox catalysis, light emittance, sensing, energy storage, biological applications, and solar fuels production. Here we review the progress of CMP research since its beginnings and offer an outlook for where these materials might be headed in the future. We also compare the prospect for CMPs against the growing range of conjugated crystalline covalent organic frameworks (COFs).

中文翻译:

共轭微孔聚合物的进展。

共轭微孔聚合物 (CMP) 是一类独特的材料,它将扩展的 π 共轭与永久微孔骨架相结合。自 2007 年被发现以来,CMP 已成为多孔材料的一个重要子类。各种合成结构单元和网络形成反应提供了种类繁多、具有不同性质和结构的 CMP。这使得 CMP 能够被开发用于气体吸附和分离、化学吸附和封装、多相催化、光氧化还原催化、光发射、传感、能量存储、生物应用和太阳能燃料生产。在这里,我们回顾了 CMP 研究自开始以来的进展,并对这些材料的未来发展方向进行了展望。我们还将 CMP 的前景与不断增长的共轭晶体共价有机框架 (COF) 的前景进行了比较。
更新日期:2020-01-29
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