当前位置: X-MOL 学术Phytochem. Lett. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Total synthesis of 2'-O-methyl-β-l-arabinosyluridine and reassignment the nucleoside from penicillium sp. as 2'-O-methyl-β-l-uridine
Phytochemistry Letters ( IF 1.3 ) Pub Date : 2020-01-28 , DOI: 10.1016/j.phytol.2020.01.018
Chunyang Shen , Haixin Ding , Xueping Tao , Ruchun Yang , Jiang Bai , Ban-Peng Cao , Yi-Yuan Peng , Qiang Xiao

In order to validate the structure of a rarely reported naturally occurring nucleoside isolated from the broth of Penicillium sp. (NO. 64), practical syntheses of 2′-O-methyl-β-l-arabinosyluridine, 2′-O-methyl-α-l-arabinosyluridine, and 2′-O-methyl-β-l-uridine were accomplished. Comparing their nuclear magnetic resonance (NMR) spectra and physical data, its structure was reassigned as 2′-O-methyl-β-l-uridine instead of former reported 2′-O-methyl-β-l-arabinosyluridine.



中文翻译:

2' - O-甲基-β-1-阿拉伯糖基尿苷的全合成并从青霉菌属sp中重新分配核苷作为2'- O-甲基-β-1-尿苷

为了验证从青霉素sp的肉汤中分离出的鲜有报道的天然存在的核苷的结构(第64),2'-的实用合成ø -甲基- β--arabinosyluridine,2'- ø -甲基- α--arabinosyluridine,和2'- ö甲基- β-尿苷被完成。比较其核磁共振(NMR)光谱和物理数据,将其结构重新分配为2' - O-甲基-β - 1-尿苷,而不是先前报道的2' - O-甲基-β - 1-阿拉伯糖基尿苷。

更新日期:2020-01-29
down
wechat
bug