Diversity of Lawesson's Reagent: Advances and Scope,Asian Journal of Organic Chemistry

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Diversity of Lawesson's Reagent: Advances and Scope
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-02-27 , DOI: 10.1002/ajoc.202000032
Krishnanka Shekhar Gayen ₁ , Nirbhik Chatterjee ₂

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Lawesson's reagent is a classic example of a compound having a remarkable construction and also a distinctive chemical behaviour that can challenge stereotype conceptual explanations. At the very beginning, it was mainly known for its use in the thionation of various types of carbonyl groups. However, over the last few years chemists reported some appealing examples which can nurture the chemistry community to perceive innovative ideas. These include the construction of valuable heterocycles, important coupling reactions, and the decoration of metal‐based attractive cores. Several important reports provided comprehensive theoretical studies regarding mechanistic classification. This article gives an overview of the recent insights and synthetic applications of this famous reagent from 2013 to 2019.

中文翻译：

Lawesson试剂的多样性：进展和范围

Lawesson试剂是具有非凡结构和独特化学行为的化合物的经典实例，可以挑战刻板印象的概念解释。从一开始，它就主要用于各种类型的羰基的硫磺化。但是，在过去的几年中，化学家们报告了一些吸引人的例子，这些例子可以培育化学界来感知创新思想。这些包括有价值的杂环的构建，重要的偶联反应以及金属基吸引核的装饰。一些重要的报告提供了有关机械分类的综合理论研究。本文概述了该著名试剂从2013年到2019年的最新见解和合成应用。

更新日期：2020-04-21

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