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Reaction of substituted phenols and alcohols with (E)-1-chloro-3,3,3-trifluoropropene (HFCO-1233zd)
Journal of Fluorine Chemistry ( IF 1.7 ) Pub Date : 2020-01-23 , DOI: 10.1016/j.jfluchem.2020.109456 Oleksii І. Mushta , Mikhail M. Kremlev , Andrey A. Filatov , Yurii L. Yagupolskii
中文翻译:
取代酚和醇与(E)-1-氯-3,3,3-三氟丙烯(HFCO-1233zd)的反应
更新日期:2020-01-24
Journal of Fluorine Chemistry ( IF 1.7 ) Pub Date : 2020-01-23 , DOI: 10.1016/j.jfluchem.2020.109456 Oleksii І. Mushta , Mikhail M. Kremlev , Andrey A. Filatov , Yurii L. Yagupolskii
Simple and convenient one-pot procedures for the preparation of ArOCH = CHCF3, ROCH = CHCF3 and CF3CH = CHOArOCH = CHCF3 starting from the industrial product HFCO-1233zd (CF3CH = CHCl) are presented. These syntheses involve the reaction of 1233zd with phenols and alcohols in the presence of potassium hydroxide in DMF or pyridine solvent at elevated temperatures.
中文翻译:
取代酚和醇与(E)-1-氯-3,3,3-三氟丙烯(HFCO-1233zd)的反应
介绍了从工业产品HFCO-1233zd(CF 3 CH = CHCl)开始的简单方便的一锅法制备ArOCH = CHCF 3,ROCH = CHCF 3和CF 3 CH = CHOArOCH = CHCF 3的方法。这些合成包括在升高的温度下,在DMF或吡啶溶剂中的氢氧化钾存在下,1233zd与酚和醇的反应。