Enantioselective Synthesis of Monosaccharide Analogues by Two‐Step Sequential Enamine Catalysis: Benzoyloxylation and Aldol Reaction,European Journal of Organic Chemistry

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Enantioselective Synthesis of Monosaccharide Analogues by Two‐Step Sequential Enamine Catalysis: Benzoyloxylation and Aldol Reaction
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-02-20 , DOI: 10.1002/ejoc.202000073
Mio Shimogaki ₁ , Aika Takeshima ₁ , Taichi Kano ₁ , Keiji Maruoka _{1,

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Affiliation

Synthesis of monosaccharide analogues in an enantio‐ and diastereoselective manner has been investigated. Asymmetric benzoyloxylation and subsequent aldol reaction using two amine catalysts effectively give monosaccharide analogues with controlled three stereogenic centers.