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High loading cotton cellulose-based aerogel self-standing electrode for Li-S batteries
Science Bulletin ( IF 18.8 ) Pub Date : 2020-01-23 , DOI: 10.1016/j.scib.2020.01.021
Heng Mao 1 , Limin Liu 1 , Lei Shi 1 , Hu Wu 1 , Jinxin Lang 1 , Ke Wang 1 , Tianxiang Zhu 1 , Yiyang Gao 1 , Zehui Sun 1 , Jing Zhao 1 , Guoxin Gao 1 , Dongyang Zhang 1 , Wei Yan 2 , Shujiang Ding 1
Affiliation  

Lithium-sulfur (Li-S) batteries have attracted considerable attention due to their high energy density (2600 Wh kg−1). However, its commercialization is hindered seriously by the low loading and utilization rate of sulfur cathodes. Herein, we designed the cellulose-based graphene carbon composite aerogel (CCA) self-standing electrode to enhance the performance of Li-S batteries. The CCA contributes to the mass loading and utilization efficiency of sulfur, because of its unique physical structure: low density (0.018 g cm−3), large specific surface area (657.85 m2 g−1), high porosity (96%), and remarkable electrolyte adsorption (42.25 times). Compared to Al (about 49%), the CCA displayed excellent sulfur use efficiency (86%) and could reach to high area capacity of 8.60 mAh cm−2 with 9.11 mg S loading. Meanwhile, the CCA exhibits the excellent potential for pulse sensing applications due to its flexibility and superior sensitivity to electrical response signals.



中文翻译:

用于锂硫电池的高负载棉纤维素基气凝胶自立电极

锂硫 (Li-S) 电池因其高能量密度 (2600 Wh kg -1 ) 而备受关注。然而,硫正极的负载量和利用率低,严重阻碍了其商业化。在此,我们设计了基于纤维素的石墨烯碳复合气凝胶(CCA)自立电极,以提高锂硫电池的性能。CCA 有助于提高硫的质量负载和利用效率,因为它具有独特的物理结构:低密度 (0.018 g cm −3 )、大比表面积 (657.85 m 2 g −1)、高孔隙率(96%)和显着的电解质吸附(42.25倍)。与 Al(约 49%)相比,CCA 显示出出色的硫利用效率(86%),并且可以在 9.11 mg S 负载下达到 8.60 mAh cm -2的高面积容量。同时,由于其灵活性和对电响应信号的卓越灵敏度,CCA 在脉冲传感应用方面展现出卓越的潜力。

更新日期:2020-01-23
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