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Two-dimensional MnFeCo layered double oxide as catalyst for enhanced selective catalytic reduction of NOx with NH3 at low temperature (25–150 °C)
Applied Catalysis A: General ( IF 4.7 ) Pub Date : 2020-01-22 , DOI: 10.1016/j.apcata.2020.117432
Xia Zhou , Feng Yu , Ruobing Sun , Junqi Tian , Qiang Wang , Bin Dai , Jianming Dan , Heriberto Pfeiffer

Low temperature catalysts for selective catalytic reduction of NOx with NH3 plays an important role in flue gas treatments. Here, a two-dimensional MnFeCo layered double oxide were synthetized, characterized and employed as NH3 selective catalytic reduction catalyst, showing excellent low temperature de-NOx performance. MnFeCo layered double oxide exhibited a specific surface area of 92 m2/g with average pore size and volume of 2 nm and 1.5 cm3/g. At 100 °C, the MnFeCo layered double oxide performed an efficient NO conversion of 100 %. Even at 25 and 50 °C, NO conversions reached values of 49 and 86 %, respectively. Furthermore, the NO conversion reached an efficiency of 89 % in the presence of H2O vapor (5 %) and SO2 (100 ppm). Based on that, it can be said that this NH3 selective catalytic reduction catalyst shows great potential in NOx denitration of stationary industrial installations at a low temperature range.



中文翻译:

二维MnFeCo层状双氧化物作为催化剂,可在低温(25–150°C)下增强NH 3对NO x的选择性催化还原

用于用NH 3选择性催化还原NO x的低温催化剂在烟道气处理中起重要作用。在这里,二维MnFeCo层状双氧化物被synthetized,其特征在于并用作NH 3选择性催化还原催化剂,表示脱NO优异的低温X性能。MnFeCo层状双氧化物的比表面积为92 m 2 / g,平均孔径和体积为2 nm和1.5 cm 3/G。在100°C下,MnFeCo层状双氧化物的有效NO转化率为100%。即使在25和50°C,NO转化率也分别达到49%和86%。另外,在H 2 O蒸气(5%)和SO 2(100ppm)的存在下,NO转化率达到89%。基于此,可以说该NH 3选择性催化还原催化剂在固定的工业设备在低温范围内的NO x脱硝中显示出很大的潜力。

更新日期:2020-01-22
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