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Supercritical ethanol deposition of Ni(OH)2 nanosheets on carbon cloth for flexible solid-state asymmetric supercapacitor electrode
The Journal of Supercritical Fluids ( IF 3.4 ) Pub Date : 2020-01-22 , DOI: 10.1016/j.supflu.2020.104774
Qiang Zou , Diab Khalafallah , Zongxiao Wu , Jianhui Chen , Mingjia Zhi , Zhanglian Hong

Ni(OH)2 nanosheets (NSs) were grown onto an electrochemically activated carbon cloth (ECC) with a self-supported microstructure by using efficient ethanol assisted supercritical deposition method. Benefited from the structural features of the well-developed porous architecture with effective channels for electrolyte ions diffusion and accessible redox sites, the nano-heterostructure brings a high utilization of electroactive material and thereby good electrochemical performance. The specific capacity of 918 mC cm−2 at 2 mA cm−2 with good rate performance (68.4 % retention at 20 mA cm−2) was achieved for the obtained Ni(OH)2 NSs/ECC flexible electrode. The assembled flexible solid-state device with a 1.8 V operating potential displays an energy density of 8.3 mW h cm-3 at 20 mW cm-3. Additionally, the as-fabricated device reveals cyclic stability with 87 % capacity retention (10,000 cycles at 50 mA cm−2). These results show the importance of supercritical fluid deposition as a potential method for supercapacitors electrode.



中文翻译:

Ni(OH)2纳米片在碳布上的超临界乙醇沉积,用于柔性固态不对称超级电容器电极

通过使用高效的乙醇辅助超临界沉积方法,将Ni(OH)2纳米片(NSs)生长在具有自支撑微结构的电化学活性炭布(ECC)上。得益于发达的多孔结构的结构特征,该结构具有有效的电解质离子扩散通道和可访问的氧化还原位点,纳米异质结构带来了电活性材料的高利用率,从而具有良好的电化学性能。对于所获得的Ni(OH)2,在2 mA cm -2时的比容量为918 mC cm -2,具有良好的速率性能(在20 mA cm -2时保留率为68.4%)。NSs / ECC柔性电极。用1.8 V工作电位显示器的8.3毫瓦高厘米的能量密度组装的柔性固态器件-3以20mW厘米-3。另外,所制造的装置显示出具有87%容量保持率的循环稳定性(在50 mA cm -2时10,000个循环)。这些结果表明,超临界流体沉积作为超级电容器电极的潜在方法的重要性。

更新日期:2020-01-22
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