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Rhodium(III)‐Catalyzed Directed C−H Bond Naphthylation with 7‐Azabenzonorbornadiene as the Naphthylating Reagent
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-01-30 , DOI: 10.1002/ajoc.202000029
Honghe Li 1 , Weicong Guo 1 , Jijun Jiang 1 , Jun Wang 1
Affiliation  

An efficient rhodium(III)‐catalyzed C−H bond naphthylation reaction is described for the synthesis of diverse anilides and benzamides bearing naphthyl substituents. The substrate scope is broad. The products could be facilely elaborated to various synthetically useful intermediates. To the best of our knowledge, using 7‐azabenzonorbornadienes to achieve naphthylation via transition‐metal‐catalyzed C−H activation has not been reported before.

中文翻译:

铑(III)催化的7-氮杂苯并降冰片二烯作为萘化试剂的定向C H键萘化

描述了一种有效的铑(III)催化的CH键与萘基化反应,用于合成带有萘基取代基的各种酸酐和苯甲酰胺。基材范围很广。该产物可以容易地制成各种合成有用的中间体。据我们所知,以前还没有报道使用7-氮杂苯并降冰片二烯通过过渡金属催化的CH活化来实现萘化。
更新日期:2020-01-31
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