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Hydroboration of Aldehydes, Ketones, and Carbodiimides Promoted by Mono(imidazolin‐2‐iminato) Hafnium Complexes
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-01-21 , DOI: 10.1002/ejoc.201901750
Maxim Khononov 1 , Natalia Fridman 1 , Matthias Tamm 2 , Moris S. Eisen 1
Affiliation  

The synthesis and characterization of a new series of highly oxophilic mono(imidazolin‐2‐iminato)hafnium tribenzyl complexes is presented. Those complexes were found to be active catalysts promoting the hydroboration of aldehydes, ketones, and the selective monohydroboration of carbodiimides with HBpin.
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中文翻译:

单(咪唑啉-2-亚胺基)Ha配合物促进的醛,酮和碳二亚胺的硼氢化

介绍了一系列新的高度亲氧的单(咪唑啉-2-亚氨基))三苄基配合物的合成和表征。发现这些络合物是促进醛,酮的氢硼化以及碳二亚胺与HBpin选择性单氢硼化的活性催化剂。
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更新日期:2020-01-21
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