Nitrogen fixation is a topic of continuing interest to researchers from generation to generation. Owing to the unique characteristics of plasma, its application to nitrogen fixation has recently attracted attention in the distributed chemical manufacturing field, i.e., making fertilizers on site. The incorporation of nitrogen as either ‘lattice nitrogen’ or ‘chemical nitrogen’, composing functional groups through plasma technology to form nitrogen-containing nanomaterials, is of great importance, since various properties or new functionalities can be achieved for nanomaterials with suitable nitrogen content. This review looks at the state of the art. Firstly, based on generated N-containing nanomaterials such as nitrides, carbonitrides, oxynitrides, oxycarbonitride, and N-doped/implanted nanostructures, the developed plasma-assisted processes and typical cases are classified and displayed. Possible mechanisms related to the N-fixation process using NH 3 and N 2

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纳米材料中的等离子体辅助固氮：制备，表征和应用

固氮是研究者一代又一代不断关注的话题。由于等离子体的独特特性，其在固氮中的应用近来引起了分布式化学制造领域的关注，即在现场制造肥料。通过等离子技术结合官能团以形成含氮纳米材料的氮作为“晶格氮”或“化学氮”的掺入非常重要，因为对于具有合适氮含量的纳米材料而言，可以获得各种性能或新的功能。这篇评论着眼于最新技术。首先，基于生成的含氮纳米材料，例如氮化物，碳氮化物，氧氮化物，氧碳氮化物和N掺杂/注入的纳米结构，对已开发的等离子辅助工艺和典型案例进行分类和显示。与使用NH 3和N 2进行固氮过程有关的可能机制