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Synthesis of 2‐(3‐Arylallylidene)‐3‐oxindoles via Dirhodium(II)‐Catalyzed Reaction of 3‐Diazoindolin‐2‐imines with 1‐Aryl‐Substituted Allylic Alcohols and Computational Insights
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-02-04 , DOI: 10.1002/adsc.201901160
Ke Gao 1 , Luyao Kou 1 , Rui Fu 1 , Xiaoguang Bao 1
Affiliation  

A straightforward approach for the synthesis of 2‐(3‐arylallylidene)‐3‐oxindoles has been achieved by the dirhodium(II)‐catalyzed reaction of 3‐diazoindolin‐2‐imines with 1‐aryl‐substituted allylic alcohols. This protocol employs easily accessible feedstocks to produce oxindole derivatives, which might be applicable in the dye industry. DFT calculations were carried out to gain a mechanistic insight into the reaction.

中文翻译:

通过二吡啶(II)催化3-重氮吲哚啉-2-亚胺与1-芳基取代的烯丙醇的反应合成2-(3-芳基亚芳基)-3-氧吲哚和计算洞察力

3-(二氮杂吲哚-2-亚胺)与1-芳基取代的烯丙醇的二价((II)催化反应已经实现了一种合成2-(3-芳基亚芳基)-3-氧吲哚的简单方法。该协议采用易于获取的原料生产羟吲哚衍生物,该衍生物可能适用于染料工业。进行DFT计算以获得对反应的机械了解。
更新日期:2020-02-04
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