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Effects of chlorinated polyethylene and antimony trioxide on recycled polyvinyl chloride/acryl-butadiene-styrene blends: Flame retardancy and mechanical properties
Polymer ( IF 4.1 ) Pub Date : 2020-01-21 , DOI: 10.1016/j.polymer.2020.122198
Yingchun Li , Lida Lv , Wensheng Wang , Jiaoxia Zhang , Jing Lin , Juying Zhou , Mengyao Dong , Yuanfa Gan , Ilwoo Seok , Zhanhu Guo

The effects of chlorinated polyethylene (CPE) and antimony trioxide (Sb2O3) on the flame retardancy and mechanical properties of the recycled polyvinyl chloride/acryl-butadiene-styrene (R–PVC/ABS) blends were investigated. The tensile strength of the blends with 40 wt% ABS, 35 wt% R–PVC and 25 wt% PVC was close to that of ABS. Both the limiting oxygen index and the vertical burning level were significantly improved, and the blends reached a flame retardant level. The notched impact strength was significantly improved with the addition of CPE. The SEM observed interpenetrating CPE network structure in the blends resulted in a significant ductile fracture of the blends. With the addition of Sb2O3, the limiting oxygen index and vertical burning grade of the blends were further improved; and the heat release rate, total heat of release and mass loss were significantly reduced. When the addition amount of CPE and Sb2O3 was 8 wt% and 6 wt% respectively, the tensile strength of the blends was 63.5 MPa, the notched impact strength was 9.2 kJ m−2, the limiting oxygen index was 31.3%, and the vertical burning grade reached V0 level. This study provides a way to reuse the polyvinyl chloride with enhanced properties.



中文翻译:

氯化聚乙烯和三氧化二锑对回收的聚氯乙烯/丙烯酸-丁二烯-苯乙烯共混物的影响:阻燃性和机械性能

研究了氯化聚乙烯(CPE)和三氧化二锑(Sb 2 O 3)对回收的聚氯乙烯/丙烯酸-丁二烯-苯乙烯(R-PVC / ABS)共混物的阻燃性和机械性能的影响。具有40 wt%ABS,35 wt%R–PVC和25 wt%PVC的共混物的拉伸强度接近ABS。极限氧指数和垂直燃烧水平都得到了显着改善,共混物达到了阻燃水平。添加CPE可以明显提高缺口冲击强度。SEM观察到共混物中互穿的CPE网络结构导致共混物显着的韧性断裂。加上Sb 2 O 3进一步提高了共混物的极限氧指数和垂直燃烧度。放热率,释放总热量和质量损失明显降低。当CPE和Sb 2 O 3的添加量分别为8 wt%和6 wt%时,共混物的拉伸强度为63.5 MPa,缺口冲击强度为9.2 kJ m -2,极限氧指数为31.3%,垂直燃烧等级达到V 0级。这项研究提供了一种重复使用具有增强性能的聚氯乙烯的方法。

更新日期:2020-01-21
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